中文核心期刊
CSCD来源期刊
中国科技核心期刊
RCCSE中国核心学术期刊

Journal of Chongqing Jiaotong University(Natural Science) ›› 2012, Vol. 31 ›› Issue (1): 168-172.DOI: 10.3969/j.issn.1674-0696.2012.01.41

Previous Articles    

Optimization of Effect Factors on Technology of Magnesium Ammonium Phosphate

Tang Qi1, Luo Guyuan2, Tang Jin2   

  1. 1. School of Science, Chongqing Jiaotong University, Chongqing 400074, China;2. College of Urban Construction & Environmental Engineering, Chongqing University, Chongqing 400030, China
  • Received:2011-05-11 Revised:2011-06-14 Online:2012-02-15 Published:2015-04-15

磷酸铵镁技术影响因素的优化

汤琪1,罗固源2,汤锦2   

  1. 1.重庆交通大学 理学院,重庆 400074;2.重庆大学 城市建设与环境工程学院,重庆 400030
  • 作者简介:汤琪(1970-),男,重庆长寿人,副教授,博士,主要从事水污染控制技术方面的研究。E-mail:tangqi99@163.com。
  • 基金资助:
    国家自然科学基金项目(50378095);重庆交通大学博士基金项目(2009kjc-015)

Abstract: The sequence of factors affecting the removal ratio of NH3-N and PO43—-P is as follows: concentration>pH> Mg∶N >P∶N> reaction time, through orthogonal experiment. The regress equation of the quantity of PO43—-P and NH3-N in the treated water is as follows: y(PO43—-P)=-3 041.57-2.76z1+2 307.2z2+3 075.5z3-2 310z2z3 (z1=pH,z2=Mg∶N,z3=P∶N), y(NH3-N)= 1 104.84-50.76z1-45.5z2-515.5z3, through once regress orthogonal experiment. The regress equation has high notability. When NH3-N is 1400 mg/L, the best treatment condition is as follows: pH=9.5, Mg∶N=1.2,P∶N=1.03, when reaction time is 30min, and stirring speed is 200r/min. On these treatment conditions, the removal ratio of PO43— is 99.73%; the quantity of PO43—-P in the treated water is 8.66 mg/L; the removal ratio of NH3-N is 98.83%; the quantity of NH3-N in the treated water is 16.45 mg/L.

Key words: magnesium ammonium phosphate, removal of nitrogen and phosphorus, effect factors, linear regression orthogonal experiment

摘要: 通过正交实验得出影响氨氮和磷酸盐去除率因素的主次顺序为:浓度>pH> Mg∶N >P∶N>反应时间。通过一次回归正交实验得出残磷量和残氮量的回归方程为:y(残磷量)=-3 041.57-2.76z1+2 307.2z2+3 075.5z3-2 310z2z3(其中z1=pH,z2=Mg∶N,z3=P∶N),y(残氮量)=1 104.84-50.76z1-45.5z2-515.5z3,回归方程高度显著。在氨氮浓度为0.1 mol/L (1 400 mg/L)及磷酸盐为相应浓度时,在兼顾处理出水的含盐量、残磷量和残氮量尽量低的前提下,最佳的实验条件为:pH=9.5,Mg∶N=1.2,P∶N=1.03,反应时间为30 min,搅拌速度为200 r/min。在上述实验条件下PO43--P的去除率为99.73%,处理出水中的PO43--P含量为8.66 mg/L,NH3-N的去除率为98.83%,NH3-N含量为16.45 mg/L。

关键词: 磷酸铵镁, 脱氮除磷, 影响因素, 一次回归正交实验

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