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Influence of Ultraviolet Aging on High-Temperature Properties of Waterborne Epoxy-SBR Emulsified Asphalt
HE Lihong1, YANG Ke1,2, MA Yuefan1,2, WEN Xianxian1,3, LI Qinglin1
2023, 42(12):
45-52.
DOI: 10.3969/j.issn.1674-0696.2023.12.07
The high-temperature properties of waterborne epoxy-SBR emulsified asphalt (WESEA) after ultraviolet aging was investigated by indoor accelerated ultraviolet light aging test. The variation law of surface morphology, high-temperature rheological properties and creep properties of WESEA binder after UV aging was explored, and the changes of WESEA binder functional groups before and after ultraviolet light aging were analyzed through infrared spectroscopy. The results show that as the content of waterborne epoxy increases, the complex shear modulus G*, rutting factor (G*/sinδ), and average elastic recovery rate γrec of the original WESEA binder and the binder after different durations of UV aging all show an increasing trend. The phase angle δ and irrecoverable creep compliance Jnr decreases, and the complex shear modulus aging index G*AI is greater than 1, indicating that waterborne epoxy increases the elastic composition of WESEA binder, effectively improves the high-temperature rheological properties of binder, and enhances the shear deformation resistance of binder. After the same UV aging duration, the functional group aging index CI′ (carbonyl C=O) and SI′(sulfoxide S=O) of WESEA binder decrease with the increase of waterborne epoxy content, but BI′ (butadienyl C=C) is similar, indicating that waterborne epoxy can effectively inhibit the oxidation reaction of the matrix asphalt and degradation of SBR latex in WESEA binder, consequently delay the UV aging process of the WESEA binder. Therefore, waterborne epoxy can effectively improve the high-temperature performance of bonding materials against UV aging.
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