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Penetration Behavior of Snow-Melting Agent Ions in Asphalt
ZHANG Qian1,2, WANG Pengtao1,2,CHANG Kailang1,2,3, FENG Wei4,PEI Xiaomei4
2024, 43(10):
19-27.
DOI: 10.3969/j.issn.1674-0696.2024.10.03
To study the permeation and diffusion behavior of snow-melting agent ions in asphalt, six kinds of snow-melting agents, including A3N (prepared from acetate, NaNO2 and urea), Ca (CH3COO)2, Mg(CH3COO)2, KCH3COO, NaCl, and NaNO2, were employed to conduct penetration experiments on asphalt. The influence of snow-melting agents on viscosity, plasticity and high-temperature stability of asphalt were investigated through changes of three major indicators. An ion chromatograph was used to detect changes of ion concentration in snow-melting agent solution and analyze the permeation and diffusion patterns of cation and anion of snow-melting agents. Based on the changes of the concentration of cations and anions of snow-melting agents during each soaking cycle, Fick's law was introduced to analyze the permeation and diffusion behavior of snow-melting agent ions in asphalt. The results show that the viscosity and plasticity of the base asphalt and SBS-modified asphalt increase after soaking with the snow-melting agent, and NaCl has the greatest impact on viscosity and plasticity. Acetate and A3N can reduce the high-temperature stability of asphalt, while NaNO2 and NaCl can improve the high-temperature stability of asphalt. The permeability of snow-melting agent ions in the base asphalt is stronger than that of the SBS-modified asphalt. The maximum diffusion intensities of cations and anions are K+ in KCH3COO and CH3COO- in Mg(CH3COO)2. After 5 cycles of permeation, the concentration of K+ in the snow-melting agent solution above the base asphalt and SBS-modified asphalt is decreased by 27.59% and 16.89%, respectively, while the concentration of CH3COO- is decreased by 35.16% and 19.38%, respectively. The Fick's law diffusion model can better describe the changes in the adsorption capacity of various ions by asphalt, among which the non-linear fitting goodness of cation adsorption capacity is higher than that of anion, making it easier to be quantified and analyzed.
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