Mechanical Properties and Microcosmic Mechanism of
Cement Mortar Modified by Graphene Oxide
YUAN Xiaoya1,YANG Yaling1,ZHOU Chao1,ZENG Junjie1,XIAO Guilan1,LIU Shaoli2
2017, 36(12):
36-42.
DOI: 10.3969/j.issn.1674-0696.2017.12.07
Graphene oxide (GO) were prepared by Hummers method and ultrasonic dispersion method; the structure was characterized by
TEM,FT-IR and X-ray photoelectron spectroscopy. The influence rules of single GO,both GO and PC addition on the flexural strength
and compressive strength of cement mortar were studied. The results indicate that with the presence of polycarboxylate
superplasticizer (PC),GO has good dispersion ability in cement-water system; after adding GO and PC,the flexural compressive
strength of cement mortar for 3 and 28 days is improved by 20% higher than that of single doped GO or single doped PC specimen,and
the strength at early stage is improved significantly. The scanning electron microscope (SEM) and the pore size analysis of cement
paste show that GO can participate in the hydration process of cement and regulate the growth of cement hydration crystal; GO modified
cement mortar C-S-H crystal can have dense,neat and regular growth on the GO layer,so the internal structure of the specimen is more
dense,which makes GO modified cement mortar exhibit excellent mechanical properties.
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